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How Solvent Affects C–H Activation and Hydrogen Production Pathways in Homogeneous Ru-Catalyzed Methanol Dehydrogenation Reactions

[Image: see text] Insights into the mechanism of the catalytic cycle for methanol dehydrogenation catalyzed by a highly active PNP pincer ruthenium complex in methanol solvent are presented, using DFT-based molecular dynamics with an explicit description of the solvent, as well as static DFT calcula...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Sinha, Vivek, Govindarajan, Nitish, de Bruin, Bas, Meijer, Evert Jan
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2018
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6080862/
https://ncbi.nlm.nih.gov/pubmed/30101037
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b01177
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