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Managing the retro-pathway in direct catalytic asymmetric aldol reactions of thioamides

Thioamides are the preferred pronucleophiles for direct catalytic asymmetric aldol reactions in the context of soft Lewis acid/hard Brønsted base cooperative catalysis. In-depth investigation of this proton-transfer catalysis, which is virtually in equilibrium, revealed that the prominence of the re...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Bao, Youmei, Kumagai, Naoya, Shibasaki, Masakatsu
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6054082/
https://ncbi.nlm.nih.gov/pubmed/30090227
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02218e
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