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Origin of stereoselectivity in the amination of alcohols using cooperative asymmetric dual catalysis involving chiral counter-ions
Asymmetric catalysis using two chiral catalysts in combination using one-pot reaction conditions is in its initial stages of development and understanding. We employ density functional theory (SMD((toluene))/M06/6-31G**,SDD(Ir)) computations to shed light on the action of chiral phosphoric acid and...
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| Publicat a: | Chem Sci |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6053974/ https://ncbi.nlm.nih.gov/pubmed/30090300 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01433g |
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