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Origin of stereoselectivity in the amination of alcohols using cooperative asymmetric dual catalysis involving chiral counter-ions

Asymmetric catalysis using two chiral catalysts in combination using one-pot reaction conditions is in its initial stages of development and understanding. We employ density functional theory (SMD((toluene))/M06/6-31G**,SDD(Ir)) computations to shed light on the action of chiral phosphoric acid and...

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Vydáno v:Chem Sci
Hlavní autoři: Tribedi, Soumi, Hadad, Christopher M., Sunoj, Raghavan B.
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6053974/
https://ncbi.nlm.nih.gov/pubmed/30090300
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01433g
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