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Pd(II)-Catalyzed Enantioselective C(sp(3))–H Arylation of Free Carboxylic Acids
An acetyl-protected aminoethyl amine (APAA) chiral ligand based on an ethylenediamine backbone was developed to achieve Pd-catalyzed enantioselective C(sp(3))–H arylation of cyclopropanecarboxylic and 2-aminoisobutyric acids without using exogenous directing groups. This new chiral catalyst affords...
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| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6038808/ https://ncbi.nlm.nih.gov/pubmed/29741883 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b03509 |
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