Mechanism of Chemical and Electrochemical N(2) Splitting by a Rhenium Pincer Complex

[Image: see text] A comprehensive mechanistic study of N(2) activation and splitting into terminal nitride ligands upon reduction of the rhenium dichloride complex [ReCl(2)(PNP)] is presented (PNP(–) = N(CH(2)CH(2)PtBu(2))(2)(–)). Low-temperature studies using chemical reductants enabled full charac...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Lindley, Brian M., van Alten, Richt S., Finger, Markus, Schendzielorz, Florian, Würtele, Christian, Miller, Alexander J. M., Siewert, Inke, Schneider, Sven
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2018
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6026835/
https://ncbi.nlm.nih.gov/pubmed/29856611
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b03755
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