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The reactivity of acyl chlorides towards sodium phosphaethynolate, Na(OCP): a mechanistic case study
The reaction of Na(OCP) with mesitoyl chloride delivers an ester functionalized 1,2,4-oxadiphosphole in a clean and P-atom economic way. The reaction mechanism has been elucidated by means of detailed NMR-spectroscopic, kinetic and computational studies. The initially formed acyl phosphaketene under...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6024182/ https://ncbi.nlm.nih.gov/pubmed/30034752 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01269h |
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