Bromide promoted hydrogenation of CO(2) to higher alcohols using Ru–Co homogeneous catalyst

Iodides are commonly used promoters in C(2+)OH synthesis from CO(2)/CO hydrogenation. Here we report the highly efficient synthesis of C(2+)OH from CO(2) hydrogenation over a Ru(3)(CO)(12)–Co(4)(CO)(12) bimetallic catalyst with bis(triphenylphosphoranylidene)ammonium chloride (PPNCl) as the cocataly...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Cui, Meng, Qian, Qingli, He, Zhenhong, Zhang, Zhaofu, Ma, Jun, Wu, Tianbin, Yang, Guanying, Han, Buxing
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6020613/
https://ncbi.nlm.nih.gov/pubmed/30155170
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01314g
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