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Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes
Heterobimetallic Pd–K carbenes featuring Pd–C(carbene)–K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp(2))P}(tBu)PdI] ([PC(sp(2))P](tBu) = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6014298/ https://ncbi.nlm.nih.gov/pubmed/30155092 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00948d |
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