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Structural switching in self-assembled metal–ligand helicate complexes via ligand-centered reactions

Ligand centered reactions are capable of conferring structural switching between a metastable, self-assembled Fe–iminopyridine aggregate and a stable M(2)L(3) helicate. The reactivity is directed and accelerated by the stability of the final product structure. Under aerobic conditions, both substitu...

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Publicat a:Chem Sci
Autors principals: Holloway, Lauren R., McGarraugh, Hannah H., Young, Michael C., Sontising, Watit, Beran, Gregory J. O., Hooley, Richard J.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6014161/
https://ncbi.nlm.nih.gov/pubmed/30155089
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01038e
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