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Symmetry of octa-coordination environment has a substantial influence on dinuclear Tb(III) triple-decker single-molecule magnets

Single-molecule magnet (SMM) properties of terbium(iii)-phthalocyaninato and porphyrinato mixed ligand triple-decker complexes, [(TTP)Tb(Pc)Tb(TTP)] (1) and [(Pc)Tb(Pc)Tb(TTP)] type (2), were studied and were compared with those of the Tb(III) homoleptic triple-decker complex [(obPc)Tb(obPc)Tb(obPc)...

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Vydáno v:Chem Sci
Hlavní autoři: Katoh, Keiichi, Breedlove, Brian K., Yamashita, Masahiro
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2016
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6013818/
https://ncbi.nlm.nih.gov/pubmed/30155079
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04669f
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