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The auxiliary [4Fe–4S] cluster of the Radical SAM heme synthase from Methanosarcina barkeri is involved in electron transfer

The heme synthase AhbD catalyzes the oxidative decarboxylation of two propionate side chains of iron-coproporphyrin III to the corresponding vinyl groups of heme during the alternative heme biosynthesis pathway occurring in sulfate-reducing bacteria and archaea. AhbD belongs to the family of Radical...

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Pubblicato in:Chem Sci
Autori principali: Kühner, Melanie, Schweyen, Peter, Hoffmann, Martin, Ramos, José Vazquez, Reijerse, Edward J., Lubitz, Wolfgang, Bröring, Martin, Layer, Gunhild
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6013774/
https://ncbi.nlm.nih.gov/pubmed/30155111
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01140c
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