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Ring-opening copolymerization thermodynamics and kinetics of γ-valerolactone/ϵ-caprolactone

The general misconception that γ-lactones are not thermodynamically polymerizable has limited the development of all γ-lactone-based copolymers. A few studies have reported copolymerization of these five-membered cyclic esters with more reactive monomers, yet a systematic investigation of kinetics a...

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Publicat a:PLoS One
Autors principals: Gagliardi, Mariacristina, Bifone, Angelo
Format: Artigo
Idioma:Inglês
Publicat: Public Library of Science 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6013151/
https://ncbi.nlm.nih.gov/pubmed/29927986
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1371/journal.pone.0199231
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