Selective carboxylation of reactive benzylic C–H bonds by a hypervalent iodine(III)/inorganic bromide oxidation system

An oxidation system comprising phenyliodine(III) diacetate (PIDA) and iodosobenzene with inorganic bromide, i.e., sodium bromide, in an organic solvent led to the direct introduction of carboxylic acids into benzylic C–H bonds under mild conditions. The unique radical species, generated by the homol...

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Bibliographic Details
Published in:Beilstein J Org Chem
Main Authors: Dohi, Toshifumi, Ueda, Shohei, Iwasaki, Kosuke, Tsunoda, Yusuke, Morimoto, Koji, Kita, Yasuyuki
Format: Artigo
Language:Inglês
Published: Beilstein-Institut 2018
Subjects:
Letter
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6009330/
https://ncbi.nlm.nih.gov/pubmed/29977380
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.94
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