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Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes
A sulfenium-ion-initiated, catalytic, enantio-selective polyene cyclization is described. Homogeranylar-enes and ortho-geranylphenols undergo polycyclization in good yield, diastereoselectivity, and enantioselectivity. The stereodetermining step is the generation of an enantio-merically enriched thi...
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| Publicado no: | J Am Chem Soc |
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| Principais autores: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6008787/ https://ncbi.nlm.nih.gov/pubmed/29509003 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01660 |
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