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Comment on “A quantitative definition of hypervalency” by M. C. Durrant, Chem. Sci., 2015, 6, 6614

Consideration is given to (electronically) hypervalent increased-valence structures, which possess 2c–1e bonds, fractional 2c–2e bonds, and usually normal 2c–2e bonds. For singlet-spin electron-rich systems, increased-valence structures, with Heitler–London 2c–2e bond wavefunctions, are equivalent t...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Harcourt, Richard D., Klapötke, Thomas M.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6007126/
https://ncbi.nlm.nih.gov/pubmed/29999045
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04866d
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