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SuFEx Chemistry of Thionyl Tetrafluoride (SOF(4)) with Organolithium Nucleophiles: Synthesis of Sulfonimidoyl Fluorides, Sulfoximines, Sulfonimidamides and Sulfonimidates

Thionyl tetrafluoride (SOF(4)) is a valuable connective gas for sulfur fluoride exchange (SuFEx) click chemistry, that enables multidimensional linkages to be created via sulfur–oxygen (S–O) and sulfur–nitrogen (S–N) bonds. In this report, we expand the available SuFEx chemistry of SOF(4) to include...

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發表在:Angew Chem Int Ed Engl
Main Authors: Gao, Bing, Li, Suhua, Wu, Peng, Moses, John E., Sharpless, K. Barry
格式: Artigo
語言:Inglês
出版: 2018
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6005182/
https://ncbi.nlm.nih.gov/pubmed/29314580
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201712145
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