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Chemoselective nitro reduction and hydroamination using a single iron catalyst

The reduction and reductive addition (formal hydroamination) of functionalised nitroarenes is reported using a simple and bench-stable iron(iii) catalyst and silane. The reduction is chemoselective for nitro groups over an array of reactive functionalities (ketone, ester, amide, nitrile, sulfonyl an...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Zhu, Kailong, Shaver, Michael P., Thomas, Stephen P.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6005157/
https://ncbi.nlm.nih.gov/pubmed/29997793
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04471e
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