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What determines if a ligand activates or passivates a superatom cluster?
Quantum confinement in small metal clusters leads to a bunching of states into electronic shells reminiscent of shells in atoms, enabling the classification of clusters as superatoms. The addition of ligands tunes the valence electron count of metal clusters and appears to serve as protecting groups...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6005155/ https://ncbi.nlm.nih.gov/pubmed/29997798 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04293c |
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