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Vacancy defect configurations in the metal–organic framework UiO-66: energetics and electronic structure

Vacancy lattice sites in the metal–organic framework UiO-66 are known to have a profound effect on the material properties. Here we use density functional theory to compare the energies of defect arrangements containing missing linkers and missing metal clusters for different choices of charge compe...

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Pubblicato in:J Mater Chem A Mater
Autori principali: Svane, Katrine L., Bristow, Jessica K., Gale, Julian D., Walsh, Aron
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6003546/
https://ncbi.nlm.nih.gov/pubmed/30009026
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7ta11155j
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