A flexible, redox-active macrocycle enables the electrocatalytic reduction of nitrate to ammonia by a cobalt complex

The cobalt macrocycle complex [Co(DIM)Br(2)](+) (DIM = 2,3-dimethyl-1,4,8,11-tetraazacyclotetradeca-1,3-diene) is an electrocatalyst for the selective reduction of nitrate to ammonia in aqueous solution. The catalyst operates over a wide pH range and with very high faradaic efficiency, albeit with l...

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Vydáno v:Chem Sci
Hlavní autoři: Xu, Song, Ashley, Daniel C., Kwon, Hyuk-Yong, Ware, Gabrielle R., Chen, Chun-Hsing, Losovyj, Yaroslav, Gao, Xinfeng, Jakubikova, Elena, Smith, Jeremy M.
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5994878/
https://ncbi.nlm.nih.gov/pubmed/29938022
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00721g
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