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Stereoselective Dynamic Cyclization of Allylic Azides: Synthesis of Tetralins, Chromanes, and Tetrahydroquinolines
This report describes the stereoselective synthesis of 3-azido-tetralins, -chromanes, and -tetrahy-droquinolines via a tandem allylic azide rearrangement/Friedel–Crafts alkylation. Exposure of allylic azides with a pendant trichloroacetimidate to catalytic quantities of AgSbF(6) proved optimal for t...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5989720/ https://ncbi.nlm.nih.gov/pubmed/29303567 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b11299 |
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