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Precise synthesis of sulfur-containing polymers via cooperative dual organocatalysts with high activity

Metal-free and controlled synthesis of sulfur-containing polymer is still a big challenge in polymer chemistry. Here, we report a metal-free, living copolymerization of carbonyl sulfide (COS) with epoxides via the cooperative catalysis of organic Lewis pairs including bases (e.g.: phosphazene, amidi...

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Publicat a:Nat Commun
Autors principals: Zhang, Cheng-Jian, Wu, Hai-Lin, Li, Yang, Yang, Jia-Liang, Zhang, Xing-Hong
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5976647/
https://ncbi.nlm.nih.gov/pubmed/29849024
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-04554-5
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