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Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights

Advancing the rational design of main-group N-heterocyclic carbene complexes, this study reports the synthesis, X-ray crystallographic and NMR spectroscopic characterisation of a novel series of Ga complexes containing neutral or anionic NHC ligands using the unsaturated carbene IPr (IPr = 1,3-bis-(...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Uzelac, Marina, Hernán-Gómez, Alberto, Armstrong, David R., Kennedy, Alan R., Hevia, Eva
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5975842/
https://ncbi.nlm.nih.gov/pubmed/29910864
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02086g
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