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Negative ion photoelectron spectroscopy confirms the prediction that D(3h) carbon trioxide (CO(3)) has a singlet ground state
The CO(3) radical anion (CO(3)˙(–)) has been formed by electrospraying carbonate dianion (CO(3)(2–)) into the gas phase. The negative ion photoelectron (NIPE) spectrum of CO(3)˙(–) shows that, unlike the isoelectronic trimethylenemethane [C(CH(2))(3)], D(3h) carbon trioxide (CO(3)) has a singlet gro...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5975725/ https://ncbi.nlm.nih.gov/pubmed/29910870 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03542b |
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