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Negative ion photoelectron spectroscopy confirms the prediction that D(3h) carbon trioxide (CO(3)) has a singlet ground state

The CO(3) radical anion (CO(3)˙(–)) has been formed by electrospraying carbonate dianion (CO(3)(2–)) into the gas phase. The negative ion photoelectron (NIPE) spectrum of CO(3)˙(–) shows that, unlike the isoelectronic trimethylenemethane [C(CH(2))(3)], D(3h) carbon trioxide (CO(3)) has a singlet gro...

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Bibliografische gegevens
Gepubliceerd in:Chem Sci
Hoofdauteurs: Hrovat, David A., Hou, Gao-Lei, Chen, Bo, Wang, Xue-Bin, Borden, Weston Thatcher
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Royal Society of Chemistry 2016
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5975725/
https://ncbi.nlm.nih.gov/pubmed/29910870
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03542b
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