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Identification of a biliverdin geometric isomer by means of HPLC/ESI–MS and NMR spectroscopy. Differentiation of the isomers by using fragmentation “in-source”

ABSTRACT: A commercially available biliverdin sample was analyzed by means of HPLC/ESI–MS and NMR spectroscopy. It was been found that beside the main IXα 5Z,10Z,15Z isomer, the sample contains also the geometric isomer IXα 5Z,10Z,15E. It was also found the isomers behave differentially upon “in-sou...

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Detalhes bibliográficos
Publicado no:Monatsh Chem
Main Authors: Frański, Rafał, Gierczyk, Błażej, Popenda, Łukasz, Kasperkowiak, Małgorzata, Pędzinski, Tomasz
Formato: Artigo
Idioma:Inglês
Publicado em: Springer Vienna 2018
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5972171/
https://ncbi.nlm.nih.gov/pubmed/29887645
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-018-2161-7
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