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Glycosyl nitrates in synthesis: streamlined access to glucopyranose building blocks differentiated at C-2(†)
In an attempt to refine a CAN-mediated synthesis of 1,3,4,6-tetra-O-acetyl-α-D-glucopyranose (2-OH glucose) we unexpectedly discovered that this reaction proceeds via the intermediacy of glycosyl nitrates. Improved mechanistic understanding of this reaction led to the development of a more versatile...
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| Veröffentlicht in: | Org Biomol Chem |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5971085/ https://ncbi.nlm.nih.gov/pubmed/29693690 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8ob00477c |
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