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Redox-ligand sustains controlled generation of CF(3) radicals by well-defined copper complex
A well-defined copper complex bearing iminosemiquinone ligands performs single electron reduction of an electrophilic CF(3)(+) source into CF˙3 radicals. This redox behavior is enabled by the ligand which shuttles through two different redox states (iminosemiquinone and iminobenzoquinone) while the...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5968567/ https://ncbi.nlm.nih.gov/pubmed/29899928 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03636d |
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