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Crystal structure of the acyclic form of 1-de­oxy-1-[(4-methoxyphenyl)(methyl)amino]-d-fructose

The title compound, C(14)H(21)NO(6), (I), crystallizes exclusively in the acyclic keto form. In solution of (I), the acyclic tautomer represents only 10% of the population in equilibrium, with the other 90% consisting of β-pyran­ose, β-furan­ose, α-pyran­ose, and α-furan­ose cyclic forms. The carboh...

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發表在:Acta Crystallogr E Crystallogr Commun
Main Authors: Mossine, Valeri V., Barnes, Charles L., Mawhinney, Thomas P.
格式: Artigo
語言:Inglês
出版: International Union of Crystallography 2018
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5956321/
https://ncbi.nlm.nih.gov/pubmed/29850038
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989018000099
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