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Origins of halogen effects in bioorthogonal sydnone cycloadditions()
Halogen substituents increase sydnone cycloaddition reactivities substantially. Fluoro-sydnones are superior to bromo- and chloro-sydnones, and can achieve extremely high second-order rate constants with strained alkynes. Computational studies have revealed the fluorine substituent increases the rea...
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| Veröffentlicht in: | Chem Commun (Camb) |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5953849/ https://ncbi.nlm.nih.gov/pubmed/29707720 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc02128g |
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