Enhancement of CO(2) Uptake and Selectivity in a Metal–Organic Framework by the Incorporation of Thiophene Functionality

[Image: see text] The complex [Zn(2)(tdc)(2)dabco] (H(2)tdc = thiophene-2,5-dicarboxylic acid; dabco = 1,4-diazabicyclooctane) shows a remarkable increase in carbon dioxide (CO(2)) uptake and CO(2)/dinitrogen (N(2)) selectivity compared to the nonthiophene analogue [Zn(2)(bdc)(2)dabco] (H(2)bdc = be...

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發表在:Inorg Chem
Main Authors: Bolotov, Vsevolod A., Kovalenko, Konstantin A., Samsonenko, Denis G., Han, Xue, Zhang, Xinran, Smith, Gemma L., McCormick, Laura J., Teat, Simon J., Yang, Sihai, Lennox, Matthew J., Henley, Alice, Besley, Elena, Fedin, Vladimir P., Dybtsev, Danil N., Schröder, Martin
格式: Artigo
語言:Inglês
出版: American Chemical Society 2018
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5951605/
https://ncbi.nlm.nih.gov/pubmed/29683657
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b00138
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