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The first chiral diene-based metal–organic frameworks for highly enantioselective carbon–carbon bond formation reactions
We have designed the first chiral diene-based metal–organic framework (MOF), E(2)-MOF, and postsynthetically metalated E(2)-MOF with Rh(i) complexes to afford highly active and enantioselective single-site solid catalysts for C–C bond formation reactions. Treatment of E(2)-MOF with [RhCl(C(2)H(4))(2...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5951194/ https://ncbi.nlm.nih.gov/pubmed/29861953 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02100f |
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