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Identification of diborane(4) with bridging B–H–B bonds

The irradiation of diborane(6) dispersed in solid neon at 3 K with tunable far-ultraviolet light from a synchrotron yielded a set of IR absorption lines, the pattern of which implies a carrier containing two boron atoms. According to isotope effects and quantum-chemical calculations, we identified t...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Chou, Sheng-Lung, Lo, Jen-Iu, Peng, Yu-Chain, Lin, Meng-Yeh, Lu, Hsiao-Chi, Cheng, Bing-Ming, Ogilvie, J. F.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5951111/
https://ncbi.nlm.nih.gov/pubmed/29861928
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02586a
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