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Control of cerium oxidation state through metal complex secondary structures
A series of alkali metal cerium diphenylhydrazido complexes, M(x)(py)(y)[Ce(PhNNPh)(4)], M = Li, Na, and K, x = 4 (Li and Na) or 5 (K), and y = 4 (Li), 8 (Na), or 7 (K), were synthesized to probe how a secondary coordination sphere would modulate electronic structures at a cerium cation. The resulti...
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Publicado no: | Chem Sci |
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Main Authors: | , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
Royal Society of Chemistry
2015
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5951102/ https://ncbi.nlm.nih.gov/pubmed/29861931 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02607e |
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