The preparation of an ultrastable mesoporous Cr(iii)-MOF via reductive labilization

Kinetic labilization of the Fe(iii)–O coordination bond in a mesoporous metal–organic framework, PCN-333-Fe(iii), is realized by the reduction of Fe(iii) by Cr(ii). The Fe(ii)–Cr(ii) metathesis is thus completely achieved followed by this reductive labilization process that generates PCN-333-Cr(iii)...

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Udgivet i:Chem Sci
Main Authors: Lian, Xizhen, Feng, Dawei, Chen, Ying-Pin, Liu, Tian-Fu, Wang, Xuan, Zhou, Hong-Cai
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2015
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5947515/
https://ncbi.nlm.nih.gov/pubmed/29861943
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02587g
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