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Comparison of rhenium–porphyrin dyads for CO(2) photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy
We report a study of the photocatalytic reduction of CO(2) to CO by zinc porphyrins covalently linked to [Re(I)(2,2′-bipyridine)(CO)(3)L](+/0) moieties with visible light of wavelength >520 nm. Dyad 1 contains an amide C(6)H(4)NHC(O) link from porphyrin to bipyridine (Bpy), Dyad 2 contains an add...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5947513/ https://ncbi.nlm.nih.gov/pubmed/29861927 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02099a |
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