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Stepwise double excited-state proton transfer is not possible in 7-azaindole dimer

The nature of the excited-state double proton transfer in 7-azaindole (7AI) dimer—whether it is stepwise or concerted—has been under a fierce debate for two decades. Based on high-level computational simulations of static and dynamic properties, we show that much of the earlier discussions was induc...

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Publicado en:Chem Sci
Main Authors: Crespo-Otero, Rachel, Kungwan, Nawee, Barbatti, Mario
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2015
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5947511/
https://ncbi.nlm.nih.gov/pubmed/29861905
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01902h
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