Synthesis and crystallographic characterization of [2,2-bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)-3,4-bis(tri­methyl­sil­yl)-2-zircona­furan-5-one-κO (5)]triisobutyl­aluminium

The crystal structure of the title zwitterionic zirconocene complex containing a furan­one unit, [AlZr(C(10)H(15))(2)(C(4)H(9))(3)(C(9)H(18)O(2)Si(2))], is reported. On reacting a zircona­furan­one with two equivalents of HAl(i-Bu)(2), disproportionation of the Lewis acid results in the formation of...

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Detalhes bibliográficos
Publicado no:Acta Crystallogr E Crystallogr Commun
Main Authors: Burlakov, Vladimir V., Bogdanov, Vyacheslav S., Arndt, Perdita, Spannenberg, Anke, Rosenthal, Uwe, Beweries, Torsten, Shur, Vladimir B.
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2018
Assuntos:
Research Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5946991/
https://ncbi.nlm.nih.gov/pubmed/29765769
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989018004759
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