Chiral macrocyclic terpyridine complexes

The syntheses of novel chiral M(ii) bis(terpyridine) cage complexes Fe(L1)(2)-c and Ru(L1)(2)-c are described. The extraordinary design of the precursors Fe(L1)(2) and Ru(L1)(2) allows perfect preorganization for the final closing step. Due to the rigidity of the spacers between the two terpyridine...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Brandl, Thomas, Hoffmann, Viktor, Pannwitz, Andrea, Häussinger, Daniel, Neuburger, Markus, Fuhr, Olaf, Bernhard, Stefan, Wenger, Oliver S., Mayor, Marcel
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2018
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5941204/
https://ncbi.nlm.nih.gov/pubmed/29780516
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05285e
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