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Using stereoretention for the synthesis of E-macrocycles with ruthenium-based olefin metathesis catalysts

The synthesis of E-macrocycles is achieved using stereoretentive, Ru-based olefin metathesis catalysts supported by dithiolate ligands. Kinetic studies elucidate marked differences in activity among the catalysts tested, with catalyst 4 providing meaningful yields of products in much shorter reactio...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Ahmed, Tonia S., Montgomery, T. Patrick, Grubbs, Robert H.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5934820/
https://ncbi.nlm.nih.gov/pubmed/29780490
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00435h
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