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Unexpected solvation-stabilisation of ions in a protic ionic liquid: insights disclosed by a bond energetic study
Equilibrium acidities (pK(a)s) of 42 organic acids were precisely determined in protic ionic liquid (PIL) [DBUH][OTf]. Surprisingly, the often seen homoassociation complication during the pK(a) measurement of O–H acids in DMSO was not detected in [DBUH][OTf], implying that the incipient oxanion shou...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Royal Society of Chemistry
2018
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5934747/ https://ncbi.nlm.nih.gov/pubmed/29780485 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05227h |
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