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XBphos-Rh: a halogen-bond assembled supramolecular catalyst

The use of halogen bonding as a tool to construct a catalyst backbone is reported. Specifically, pyridyl- and iodotetrafluoroaryl-substituted phosphines were assembled in the presence of a rhodium(i) precursor to form the corresponding halogen-bonded complex XBphos-Rh. The presence of fluorine subst...

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Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Carreras, Lucas, Serrano-Torné, Marta, van Leeuwen, Piet W. N. M., Vidal-Ferran, Anton
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5934742/
https://ncbi.nlm.nih.gov/pubmed/29780494
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00233a
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