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Organocatalytic reductive coupling of aldehydes with 1,1-diarylethylenes using an in situ generated pyridine-boryl radical

A pyridine-boryl radical promoted reductive coupling reaction of aldehydes with 1,1-diarylethylenes has been established via a combination of computational and experimental studies. Density functional theory calculations and control experiments suggest that the ketyl radical from the addition of the...

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Publicat a:Chem Sci
Autors principals: Cao, Jia, Wang, Guoqiang, Gao, Liuzhou, Cheng, Xu, Li, Shuhua
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5933217/
https://ncbi.nlm.nih.gov/pubmed/29780496
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05225a
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