Hyperpolarized long-lived nuclear spin states in monodeuterated methyl groups

Monodeuterated methyl groups may support a long-lived nuclear spin state, with a relaxation time exceeding the conventional spin–lattice relaxation time T(1). Dissolution-DNP (dynamic nuclear polarization) may be used to hyperpolarize such a long-lived spin state. This is demonstrated for the CH(2)D...

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Detalhes bibliográficos
Publicado no:Phys Chem Chem Phys
Main Authors: Elliott, Stuart J., Meier, Benno, Vuichoud, Basile, Stevanato, Gabriele, Brown, Lynda J., Alonso-Valdesueiro, Javier, Emsley, Lyndon, Jannin, Sami, Levitt, Malcolm H.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5933006/
https://ncbi.nlm.nih.gov/pubmed/29595200
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cp00253c
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