New activation mechanism for half-sandwich organometallic anticancer complexes

The Cp(x) C–H protons in certain organometallic Rh(III) half-sandwich anticancer complexes [(η(5)-Cp(x))Rh(N,N′)Cl](+), where Cp(x) = Cp*, phenyl or biphenyl-Me(4)Cp, and N,N′ = bipyridine, dimethylbipyridine, or phenanthroline, can undergo rapid sequential deuteration of all 15 Cp* methyl protons i...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Banerjee, Samya, Soldevila-Barreda, Joan J., Wolny, Juliusz A., Wootton, Christopher A., Habtemariam, Abraha, Romero-Canelón, Isolda, Chen, Feng, Clarkson, Guy J., Prokes, Ivan, Song, Lijiang, O'Connor, Peter B., Schünemann, Volker, Sadler, Peter J.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2018
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5916112/
https://ncbi.nlm.nih.gov/pubmed/29732100
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05058e
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