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Direct evidence of charge separation in a metal–organic framework: efficient and selective photocatalytic oxidative coupling of amines via charge and energy transfer

The selective aerobic oxidative coupling of amines under mild conditions is an important laboratory and commercial procedure yet a great challenge. In this work, a porphyrinic metal–organic framework, PCN-222, was employed to catalyze the reaction. Upon visible light irradiation, the semiconductor-l...

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Vydáno v:Chem Sci
Hlavní autoři: Xu, Caiyun, Liu, Hang, Li, Dandan, Su, Ji-Hu, Jiang, Hai-Long
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5916110/
https://ncbi.nlm.nih.gov/pubmed/29732097
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05296k
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