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Intramolecular hydride transfer onto arynes: redox-neutral and transition metal-free C(sp(3))–H functionalization of amines
Transition metal-free intramolecular hydride transfer onto arynes is reported for the first time. This unique transformation is utilized in redox-neutral intermolecular α-functionalization reactions of different tertiary amines, generating C(sp(3))–C(sp(3)/sp(2)/sp) bonds in a single synthetic opera...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5914459/ https://ncbi.nlm.nih.gov/pubmed/29732071 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00181b |
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