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Insertion, protonolysis and photolysis reactivity of a thorium monoalkyl amidinate complex

The reactivity of the thorium monoalkyl complex Th(CH(2)SiMe(3))(BIMA)(3) [1, BIMA = MeC(N(i)Pr)(2)] with various small molecules is described. While steric congestion prohibits the insertion of N,N′-diisopropylcarbodiimide into the Th–C bond in 1, the first thorium tetrakis(amidinate) complex, Th(B...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Settineri, Nicholas S., Arnold, John
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5914426/
https://ncbi.nlm.nih.gov/pubmed/29732069
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05328b
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