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DFT Investigation of Ligand Photodissociation in [Ru(II)(tpy)(bpy)(py)](2+) and [Ru(II)(tpy)(Me(2)bpy)(py)](2+) Complexes
Photoinduced ligand dissociation of pyridine occurs much more readily in [Ru(tpy)(Me(2)bpy)(py)](2+) than in [Ru(tpy)(bpy)(py)](2+) (tpy = 2,2′:6′,2″-terpyridine; bpy = 2,2′-bipyridine, Me(2)bpy = 6,6′-dimethyl-2,2′-bipyridine; py = pyridine). The S(0) ground state and the (3)MLCT and (3)MC excited...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5901700/ https://ncbi.nlm.nih.gov/pubmed/29257679 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b02398 |
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