Solution, Solid‐State, and Computational Analysis of Agostic Interactions in a Coherent Set of Low‐Coordinate Rhodium(III) and Iridium(III) Complexes

A homologous family of low‐coordinate complexes of the formulation trans‐[M(2,2′‐biphenyl)(PR(3))(2)][BAr(F) (4)] (M=Rh, Ir; R=Ph, Cy, iPr, iBu) has been prepared and extensively structurally characterised. Enabled through a comprehensive set of solution phase (VT (1)H and (31)P NMR spectroscopy) an...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Knighton, Richard C., Emerson‐King, Jack, Rourke, Jonathan P., Ohlin, C. André, Chaplin, Adrian B.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5901041/
https://ncbi.nlm.nih.gov/pubmed/29377308
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201705990
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