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Calculating curly arrows from ab initio wavefunctions

Despite being at the heart of chemical thought, the curly arrow notation of reaction mechanisms has been treated with suspicion—the connection with rigorous molecular quantum mechanics being unclear. The connection requires a view of the wavefunction that goes beyond molecular orbitals and rests on...

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Bibliographic Details
Published in:Nat Commun
Main Authors: Liu, Yu, Kilby, Philip, Frankcombe, Terry J., Schmidt, Timothy W.
Format: Artigo
Language:Inglês
Published: Nature Publishing Group UK 2018
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5897577/
https://ncbi.nlm.nih.gov/pubmed/29651029
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-03860-2
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